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KMID : 0370219630070020072
Yakhak Hoeji
1963 Volume.7 No. 2 p.72 ~ p.74
Synthesis of Azo-steroid by Beckman-and-Schmidt Rearrangement Using Perphosphoric Acid

Abstract
Synthesis of asosteroid 3-aza-A-homo-cholestane-4-one. 3-aza-A-homo-coprostane-4-one and 3-aza-A-homo-cholestane-4-one from corresponding oxim and koto-steroid by means of Beckmann¢¥s and Schmidt¢¥s rearrangement by perphosphoric acid have been evaluated.
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